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Removal of microcystin-LR by cork-based and commercial activated carbons

dc.contributor.authorMenezes, Carina
dc.contributor.authorJosé, Sílvia
dc.contributor.authorPereira, Paulo
dc.contributor.authorSilva, Susana P.
dc.contributor.authorCarvalho, Ana P.
dc.contributor.authorMestre, Ana S.
dc.date.accessioned2016-03-02T14:00:35Z
dc.date.available2016-03-02T14:00:35Z
dc.date.issued2015-07
dc.description.abstractCyanotoxins and mainly microcystin-LR (MCLR) is a potent and ubiquitous freshwater toxin that poses a risk for human and animal health. According to the Guidelines for Drinking Water Quality published by WHO in 2011, the maximum concentration of MCLR allowed in water for human consumption is 1 g.L-1. The methods currently used to achieve effective MCLR removal are highly costly and so, the search for new, cost effective adsorbents to be incorporated in the water treatment technologies is an important issue that has been addressed by the scientific community. The present study is focused in this thematic being the first description of the application of industrial pre-treated cork derived activated carbons for the removal of MCLR. The material selected for the study was steam activated at 800 C, presenting a mesopore (0.22 cm3g-1) and micropore (0.28 cm3g-1) network [1]. Commercial activated carbons with different textural characteristics were also tested. Batch kinetic adsorption assays were performed in controlled conditions of temperature, light and agitation, and MCLR was quantified by HPLC-DAD. For MCLR concentrations between 0.5 and 8 gcm-3, after 1h of contact time the cork derived material presents removal efficiencies > 90 %. These results are identical to those of the best commercial samples, highlighting the influence of the mesopore network in the adsorption process of MCLR. The successful removal of MCLR from aqueous solutions with cork derived activated carbons may constitute a cost efficient approach to water treatment and an alternative to commercially available activated carbons.pt_PT
dc.description.sponsorshipWatercork – Valorização de subprodutos da indústria de cortiça na remoção de contaminantes (orgânicos) em águas - Cianotoxinas, Agência de Inovação (adi) - QRENpt_PT
dc.identifier.urihttp://hdl.handle.net/10400.18/3572
dc.language.isoengpt_PT
dc.peerreviewedyespt_PT
dc.subjectMicrocystin-LRpt_PT
dc.subjectCorkpt_PT
dc.subjectAdsorptionpt_PT
dc.subjectActivated Carbonspt_PT
dc.subjectCyanotoxinspt_PT
dc.subjectCianotoxinaspt_PT
dc.subjectEcotoxicologiapt_PT
dc.subjectÁgua e Solopt_PT
dc.subjectCortiçapt_PT
dc.titleRemoval of microcystin-LR by cork-based and commercial activated carbonspt_PT
dc.typeconference object
dspace.entity.typePublication
oaire.citation.conferencePlaceDresden, Alemanhapt_PT
oaire.citation.titleAnnual World Conference on Carbon - CARBON 2015, 12-17 July 2015pt_PT
rcaap.rightsrestrictedAccesspt_PT
rcaap.typeconferenceObjectpt_PT

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